• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A process for pretreating reclaimed cotton fibers to be used in the production of regenerated cellulose moldings, characterized by effective metal reduction and adjustment of the degree of polymerization and brightness, including a metal removal step and an oxidative bleaching step of the recovered cotton fibers or pulp made therefrom. Reclaimed cotton fibers treated according to the process described may be used alone or in blends with conventional chemical pulp as raw material for the production of regenerated cellulose molded articles. The process enables the technically problem-free, safe and economically feasible spinning by means of the viscose or lyocell process, whereby the present invention provides an efficient recycling possibility for cotton waste materials.
    公开号:AT515152A1
    申请号:T905/2013
    申请日:2013-11-26
    公开日:2015-06-15
    发明作者:
    申请人:Chemiefaser Lenzing Ag；
    IPC主号:
    专利说明:

    A process for pretreating recovered cotton fibers for use in the manufacture of regenerated cellulose moldings
    Summary:
    A process for pretreating recovered cotton fibers to be used in the manufacture of regenerated cellulose moldings, characterized by effective metal reduction and adjustment of the degree of polymerization and brightness, including a metal removal step and an oxidative bleaching step of the recovered cotton fibers or pulp made therefrom. Reclaimed cotton fibers treated according to the process described may be used alone or in blends with conventional chemical pulp as raw material for the production of regenerated cellulose molded articles.
    The method enables technically trouble-free, safe and economically feasible spinning by means of the viscose or lyocell method, whereby the present invention provides an efficient recycling possibility for cotton waste materials.
    The products obtained in this way are high quality regenerated cellulose regenerated cotton waste suitable for textile and nonwoven production.
    State of the art:
    According to the International Cotton Advisory Committee, 26.39 million tonnes of cotton were produced worldwide in 2012/13. About 95% of the annual cotton production is used for the production of yarns, which are subsequently used in the manufacture of textile products. Cotton textiles account for about one third of global textile production. However, significant quantities of cotton waste material are already produced during the textile production process, for example spun waste or cut waste from the packaging. This type of waste is commonly referred to as " waste prior to consumer use " sometimes referred to as " industrial waste " is known. Of course, even when a cotton-containing fabric is disposed of by the user, cotton waste, i. " waste after use by consumers ".
    Today, the majority of the cotton waste materials described are predominantly used in waste incineration or in landfills, which inevitably equates to a loss of valuable cellulose raw material.
    Only small amounts of textile cotton waste are currently being recycled. Existing recycling opportunities for cotton include, for example, the donation of used cotton textiles to charitable organizations, or the production of wipes or tearing fibers for insulation materials from consumer after-use chips. However, with the exception of resale in second-hand shops or distribution in developing countries, recycling processes usually involve downcycling of the cotton waste material, i.e., waste recycling. a product made from recycled cotton waste material is generally less valuable than the original product.
    The direct reuse of cotton waste in the manufacture of new textiles is quite narrow. One of the major problems with direct recycling is the usually shorter length of cotton fibers recovered from cotton waste material which, in addition, may be damaged due to mechanical damage to the fiber during the recovery process. Therefore, reclaimed cotton fibers for the production of high quality yarns and textiles usually need to be blended with virgin fiber. However, when recycled cotton waste material fibers are mixed with virgin fiber to make a suitable raw material for textile production, the recovered material should come from quite early stages of the textile warp. For example, if cotton waste material were recovered after dyeing a fabric, a raw material made by blending such dyed fibers with virgin fibers can be used only for the production of fabrics of a color similar to the recovered fibers. As for packaging waste, which represents a high percentage of total cotton waste, it would not be suitable for direct recycling as it is produced in many grades and colors, but usually in small quantities. U.S. Patent 5,331,801 describes the production of recycled yarns from textile waste, but the yarns made from recycled fibers require more rotations to obtain the same strength properties as yarns made from virgin fiber. The production of finer yarns suitable for the garment industry and related textile industries requires blending with up to 90% virgin fiber.
    Similarly, US Pat. No. 5,481,864 describes the production of fabric scraps from recycled fabric. Cloth remnants are first defibred to a moisture level of 10%, opened and mixed with 10 to 25% expensive high-quality carrier fresh fibers, for example with cashmere.
    The patent application WO 2011/130276 A2 describes the use of blends of fibers recovered from cotton waste materials prior to use by consumers. The patent application describes a purely mechanical process and includes extensive sorting work. It is noted that textile products made from such recovered materials include yarns containing recycled cotton material of at least three different grades. It is noted that yarns made from such recovered materials must be spun with a 15 to 30% greater twist factor than cotton virgin fiber yarns to be used in the same end product.
    The patent application US 5369861 A describes direct recycling of denim waste arising before or after use by consumers.
    The patent application WO 2011/077446 A1 describes another possibility for the mechanical recycling of textile cotton fabrics by making webs of cotton paper, cutting these webs into strips of 0.1 to 2 mm and subsequently weaving or knitting these strips into a textile fabric.
    All of the above direct recycling methods are purely mechanical, i. none of the methods involve any chemical steps, either to recover the cotton waste material, or to pre-treat the cotton waste material to make it recyclable.
    Another possibility for recycling cotton waste materials is the production of cotton hemp pulp (CRP). CRP has long been an important source of cellulosic material in papermaking, especially in the first decades of the 20th century. Therefore, the general method for producing CRP based on cooking laps with caustic is well known. Later, CRP lost importance due to the fact that a) the emerging blending of cotton with synthetic fibers complicated the production of CRP and b) the recycling of paper waste was being developed for papermaking. An advantage of converting rags into pulp is that small amounts of different grades or colors can be processed to yield large quantities of a uniform material. However, a disadvantage of CRP is that it can not be used directly as a raw material for textile production because the cellulose fibers are degraded during the CRP manufacturing process, resulting in a reduced chain length of the cellulose molecules (ie, a reduced degree of polymerization (" DP ")). leads. The direct application of CRP in textile manufacturing is also usually limited by the low brightness due to the blending of different grade and color raw materials.
    Rags suitable for the production of cotton hemp pulp may be derived either from consumer use or after use by consumers. As far as the authors are aware, the use of cotton hemp pulp for the production of cellulosic regenerate materials has not yet been disclosed.
    Methods for the production of cellulosic regenerate materials are already known to those skilled in the art: the lyocell method, which specifically uses aqueous amine oxide, in particular 4-methylmorpholine N-oxide (NMMO) (see eg EP 0356419 B1 and EP 0584318 B1), the viscose method (see for example, idol, man-made fibers by the viscose process, 1967) and the modal process (see, for example, Austrian Patent AT 287905). EP 0717131 B1 describes the production of viscose fibers from used textiles which have been dyed by means of reactive dyestuffs. The described used textiles were mechanically digested before the viscose process; however, no chemical treatment of the raw material is mentioned. For the removal of the color reductive bleaching of the alkali cellulose is mentioned. The cotton waste material from which the cotton fibers can be recovered is limited to consumer after-use textiles dyed by reactive dyes. Similar to what has been described above for the direct reuse of dyed cotton wastes, viscose fiber production according to EP 0717131 B1 requires thorough sorting of the raw materials with respect to their color. No information regarding the quality of the resulting viscose fibers is provided.
    The patent application CN 102660791A also describes the reuse of consumer consumer cotton garments by the viscose process to produce floor mats. No information is provided regarding the quality of the raw material or the obtained viscose fibers. However, the restriction of the use of such fibers to the floor mats, a rather inferior product, suggests that the quality of these fibers is low and not suitable for textile production. No. 5,601,767 describes the production of lyocell fibers by means of the Lyocell method from comminuted cellulose-containing textile fabrics. From the examples offered it is clear that the fabrics used for fiber production were of the type obtained after use by consumers. Apart from mechanical treatments, no other type of pre-treatment has been disclosed, in particular no chemical processing step is mentioned. This suggests that fibers made according to US Pat. No. 5,601,767 are useful in textile manufacture in this case as well, since dyed raw materials give dyed fibers. In addition, US 5,601,767 provides no possibility for adjusting the degree of polymerization of cotton cellulose.
    The patent CN 10219931 OB describes a method for recovering the cotton from waste polyester and cotton blend textiles by physically dissolving the cellulose content in NMMO and subsequent physical separation (filtration) of the undissolved polyester material. It is not mentioned which cellulose concentration is achieved in the prepared solution. Although the described process for dissolving cellulose in NMMO is closely related to the lyocell process using even similar stabilizing agents, the production of
    Celluloseregeneratfasern not mentioned from this solution. Therefore, this method is to be considered merely as an option for the separation of cotton from polyester, but is not suitable for recycling cotton waste material to produce regenerated cellulose fibers.
    None of the recycling possibilities described above include any chemical processes for pretreating the recovered cotton fibers prior to their use in the viscose or lyocell process.
    The above examples, which describe the state of the art for using recovered cotton fibers to make regenerated cellulosic materials, indicate that all of the processes known in the art are useful for recycling after use by consumers
    Serve cotton waste material.
    The use of consumable before use by consumers
    Cotton waste material has not been described in detail yet.
    In general, cotton consumer waste materials or cotton fibers used for textile manufacture prior to consumer use are not considered to be suitable materials for either the viscose process or the lyocell process. They consist of cellulose molecules with a high degree of polymerization (DP), i. they have a high viscosity, which is usually expressed by the intrinsic viscosity ("IV"). As a result, they become less accessible to reactants and solvents used to dissolve cellulose, and as a result become unfit for treatment in the conventional viscose or lyocell process. During the life of a piece of cotton fabric, the cellulose molecules are degraded and their DP is reduced to such a level that cotton fibers from post-consumer textile waste can eventually be used as starting materials to make cellulose regenerated fibers. However, this can not be considered a universally valid fact, as this degradation depends heavily on the conditions and the period of use. Therefore, it can not be ensured that a suitable and homogeneous DP level, which is required for the production of regenerated cellulose fibers, is generally present in post-consumer waste. Instead, after use by consumers, waste may have degraded to such an extent that the DP level is in fact too low for the production of high quality regenerated cellulose fibers.
    In waste prior to use by consumers, the high DP remains.
    In addition, the availability of recovered
    Cotton waste material is limited by the fact that textiles, in addition to cellulose, usually contain additional chemicals such as dyes, resins, optical brighteners, etc., and can be further contaminated during their life by, for example, softeners or bleaches during washing. Also, significant amounts of metals can be encountered both in pre-use and post consumer consumer cotton waste materials. On the one hand, these metals can originate from the abrasion of buttons or zippers or, on the other hand, can be incorporated into textiles during the growth into the cotton fibers or during the processing of cotton fibers.
    The presence of any of these chemicals may interfere with the use of the cotton fibers recovered from cotton waste materials in the viscose or lyocell process. For example, resins chemically bond cellulosic molecules together rendering them insoluble and unreactive. These substances are not removed from the recovered fibers by simple mechanical steps to digest the cotton waste materials.
    Particular attention must be paid to the metal content of the recovered cotton fibers, in particular as regards their use as a potential raw material for the lyocell process. It is known, for example, that iron and copper cations reduce the decomposition temperature of NMMO, the solvent in the lyocell process. At the same time the decomposition rate is increased. Accordingly, metals can also catalyze the decomposition of cellulosic dope solutions in both the viscose and lyocell processes. At elevated process temperatures or extended processing periods, this can lead to fires and explosions due to uncontrolled decomposition processes. A method of measuring the decomposition temperature is set forth in EP 0781356 B1 (" Sikarex test ").
    A high content of Si, Ca or Mg is usually associated with a high level of particulate contaminants likely to result from sand or dust. However, higher particle amounts in the spinning solutions require increased filtration effort, resulting in lower productivity. If the particle content is too high, the filtration system can even be completely blocked. In addition, large quantities of small particles which can not be removed by filtration from the dope solution can cause problems at the spinnerets, which in turn leads to low productivity and / or low quality fibers.
    Task:
    In view of this prior art, the object to be achieved has been to provide a method which allows the use of cotton grades of different grades for the production of regenerated cellulose moldings and thereby a way to efficiently recycle the cotton waste materials into high quality products suitable for e.g. the textile or nonwovens production are suitable to provide. Solution:
    This object has been achieved by a process for pretreating recovered cotton fibers to be used in the production of regenerated cellulose moldings, the pretreatment of the recovered cotton fibers comprising a metal removal step and an oxidative bleaching step.
    The present invention teaches a method of chemically pretreating cotton waste materials of any of the above types for use subsequently in the production of regenerated cellulose molded articles by the viscose or lyocell process. Thus, the present invention provides an elegant recycling option for cotton waste material and avoids inadequate disposal routes such as landfill or incineration. The molded articles made from cotton waste pretreated according to the present invention have a similar or even better quality than molded articles made from commercial " fresh " Made of chemical pulp, and are thus suitable for textile and nonwovens production.
    Cotton waste materials may be incorporated into raw materials suitable for the production of regenerated cellulose fiber by the viscose or lyocell process; for the purposes of this invention, the term " viscose " Modal methods, which are also based on the formation, spinning and regeneration of cellulose xanthate.
    The pretreatment process described in the present invention can be applied to consumer cotton waste material and / or cotton batting pulps produced therefrom before and after use. Thus, in a preferred embodiment of the present invention, the cotton fibers are recovered from waste prior to use by consumers, such as, but not limited to, comb waste, cotton trimmings or waste fibers from apparel manufacturing, and the like. In another preferred embodiment of the present invention, the cotton fibers are recovered from consumer cotton waste after use. The term " cotton waste after use by consumers " includes but is not limited to laundry waste or used clothes. In a particularly preferred embodiment, the recovered cotton fibers comprise pulp made from cotton fibers.
    Prior to the application of chemical treatments according to the present invention, it may be useful to employ mechanical treatments to properly treat the recovered fibers. This can be done by a step in which the recovered cotton fibers are mechanically comminuted, ground or opened prior to their use. Also useful, for example, depending on the source of the fibers, may be a mechanical step in which the recovered cotton fibers are separated from buttons or zippers or the like prior to their use. Also, a mechanical or chemical step in which the recovered cotton fibers are separated from non-cotton fibers prior to their use may be useful.
    The process described is a multi-step process wherein oxidative bleaching treatments are combined with acidic wash treatments and / or treatment with aqueous solutions of complexing agents. By adjusting the combination and / or the intensity of the individual steps, the described method can be used to treat any type of cotton waste material in such a way that the recovered cotton fiber material can be used as a raw material for the production of regenerated cellulose moldings. In particular, the described process effectively lowers the metal content and allows adjustment of the viscosity and brightness of the recovered cotton fibers.
    By pre-treating cotton waste materials according to the present invention, technically safe and economically feasible fiber spinning is ensured.
    Therefore, in a preferred embodiment of the process of the invention, the metal removal step is an acidic wash treatment and / or a complexing agent treatment.
    According to the present invention, cotton waste material is subjected to an acidic washing treatment to effectively lower the metal content. This is particularly important when the recovered fiber material is to be used in the lyocell process, but it is also true for the viscose process.
    The acidic wash treatment according to the present invention may take place at pH values between 1.5 and 5, preferably between 2 and 3, at temperatures from room temperature to 100 ° C, preferably from 50 to 70 ° C, for 15 to 120 minutes, preferably 15 up to 60 minutes. In a preferred embodiment, the acidic wash treatment is conducted in a manner such that the degree of polymerization of the cellulose within the cotton waste material is changed by no more than 10%, preferably less than 5%, from baseline.
    The metal removal according to the present invention may also be carried out by treating the cotton waste material with an aqueous solution of a complexing agent. Preferably, the concentration of the complexing agent in the aqueous solution is less than 5 kg per ton of oven-dried pulp (odtp) and in particular less than 2 kg / odtp. The treatment of the cotton waste material with an aqueous solution of a complexing agent may be carried out at temperatures from room temperature to 100 ° C, preferably from 50 to 80 ° C, for 15 to 120 minutes, preferably 15 to 90 minutes.
    The acidic washing step and the treatment with an aqueous solution of a complexing agent can be combined by adding the complexing agent to the acidic washing liquid in one process step.
    After the successful metal removal according to the treatments described above, a treated sample passes the Sikarex test as described in EP 0781356 B1.
    To ensure that spinning solutions suitable for use in the viscose or lyocell process can be made from the recovered cotton fibers, the degree of polymerisation of the cellulose, or, equivalently, its viscosity, usually due to the intrinsic viscosity (" IV " is set to be set to a specific range. According to the present invention, the adjustment of the viscosity can be carried out by oxidative bleaching treatments of the recovered cotton fibers. Oxidative bleaching can be conducted free of elemental chloride ("EOF"), for example by means of hypochlorides or CIO 2, or completely chlorine-free ("TCF").
    A preferred embodiment of the present invention for carrying out an oxidative bleaching treatment is bleaching the recovered cotton fibers with peroxide, which is commonly referred to by those skilled in the art as the P-stage. Peroxide bleaching according to the present invention may be at a pH of 8 to 12, preferably between 10 and 11, at temperatures of 50 to 100 ° C, preferably from 70 to 80 ° C, a reaction time of 10 to 120 minutes, preferably from 30 to 60 minutes long. The peroxide dose can be varied from 2 to 40 kg H 2 O 2 per odtp, preferably from 5 to 15 kg H 2 O 2 / odtp. A stabilizing agent, for example complexing agents, silicates, polyphosphates or Mg salts, can be added to the P-stage. Other peroxides such as peracetic acid, Caro's acid or the like are also applicable.
    In another preferred embodiment of the present invention, performing an oxidative bleaching treatment is bleaching the recovered cotton fibers with oxygen, which is commonly referred to by those skilled in the art as O-stage.
    Oxygen bleaching according to the present invention may be at a pH of 8 to 12, preferably between 10 and 11, at temperatures of 50 to 120 ° C, preferably from 80 to 100 ° C, a reaction time of 15 to 240 minutes, preferably from 60 to 90 minutes long.
    The relative oxygen pressure during the O stage may be 1 to 10 bar, preferably 3 to 6 bar.
    Another preferred embodiment of the present invention of performing an oxidative bleaching treatment is bleaching the recovered cotton fibers with ozone, which is commonly referred to by those skilled in the art as Z-stage.
    Ozone bleaching according to the present invention may be carried out at a pH of from 2 to 5, preferably between 2 and 3, at temperatures of from 30 to 90 ° C, preferably from 40 to 60 ° C, a reaction time of from 1 to 120 seconds, preferably from 1 to 10 seconds.
    The ozone dose may be varied from 0.1 to 6 kg O 2 / odtp, preferably from 1 to 3 kg 03 / odtp.
    Depending on the initial intrinsic viscosity of the cotton waste material, the conditions of the oxidative bleaching treatments may be varied to adjust the final IV of the recovered cotton fibers.
    When the recovered cotton fibers are intended to be used in the production of regenerated cellulose moldings according to the viscose process, the IV of the recovered cotton fibers should be in the range of 850 to 300 ml / g, preferably 650 to 350 ml / g, especially 550 to 400 ml / g.
    When the recovered cotton fibers are destined to be used in the production of regenerated cellulose molded articles according to the lyocell method, the IV of the recovered cotton fibers should be in the range of 650 to 300 ml / g, preferably 500 to 350 ml / g, especially 440 to 360 ml / g.
    According to the present invention, it is also possible to combine the oxidative bleaching treatments to achieve the desired IV levels with respect to the viscose or lyocell method.
    In a preferred embodiment of the present invention, oxidative bleaching treatments are performed after treating the recovered cotton fibers by acid washing or treating them with an aqueous solution of a chelating agent or a combination of both.
    An overview of the possible method embodiments is shown in FIG.
    The present invention also allows the use of dyed cotton waste materials as a source of cotton fiber recovery. By treating the dyed cotton waste material by the described method, colorant can be removed by washing during the acid wash treatment and / or by destroying the chromophores during the oxidative bleach treatments. Thus, the brightness of the recovered cotton fiber material can be adjusted to the desired level by oxidative bleaching. Preferably, according to the present invention, the brightness is adjusted to> 80% ISO by an oxidative bleaching step.
    Another part of the present invention is the use of the recovered cotton fibers obtained by the above-described method in the production of a regenerated cellulose molded body according to the viscose method.
    The molded article obtained in this way may be a staple fiber, a filament fiber, a sponge or a viscose or modal type film.
    Another preferred embodiment of the present invention is the use of the recovered cotton fibers obtained by the above-described method in the production of a regenerated cellulose molded article according to the lyocell method.
    The molded article obtained in this way may be a staple fiber, a filament fiber, a sponge or a lyocell-type film.
    The recovered cellulosic fibers can be used in the preparation of such regenerated cellulose molded articles, either in pure form or in blends with commercial chemical pulp, and the resulting molded articles can be used for further processing into textile or nonwoven products.
    Advantages when using the described method:
    Pretreating pre-or post-consumer cotton waste or cotton hemp pulp made therefrom according to the present invention offers several advantages over the production of regenerated cellulose molded articles by the viscose or lyocell process as compared to untreated cotton waste.
    An advantage of the present invention is that by means of the described method the total metal content of the recovered cotton fibers is reduced to a level which enables the preparation of thermally stable spinning solutions.
    Another advantage of the present invention is that by means of the described process the total metal content of the recovered cotton fibers is effectively reduced. Less particles in the spinning solutions (viscose and lyocell) gives better processability.
    Another advantage of the present invention is that by means of the described method the intrinsic viscosity of the recovered cotton fibers can be adjusted in a wide range. Thus, the present invention makes it possible to use any type of cotton waste material or cotton hemp pulp made therefrom before or after use for the production of regenerated cellulose molded articles by the viscose or lyocell process.
    Another advantage of the present invention is that by subjecting the recovered cotton fibers to the described process, their brightness can be adjusted in a wide range. Thus, the present invention allows
    Invention to use cotton fibers recovered from cotton waste materials of several different original colors for the production of regenerated cellulose moldings.
    Yet another advantage of the present invention is that, by subjecting reclaimed cotton fibers to the described process, the production of regenerated cellulose molded articles by the viscose or lyocell process has similar or even better properties than those made from conventional chemical pulp , is possible.
    Finally, another advantage of the present invention is that recovered cellulosic fibers obtained by the process described can be used either by themselves or in blends with commercial chemical pulp.
    Examples:
    Example 1:
    A lyocell spinning solution was prepared from Sample 1, untreated recovered cotton fibers from dyed consumer cotton waste material in the form of cotton hemp pulp. This spinning solution was subjected to the Sikarex test without any pretreatment. This spinning solution did not pass the Sikarex test.
    Example 2:
    Another lyocell spinning solution was made from Sample 2, which was untreated cotton recovered from indigo denim waste prior to consumer use. Due to the high viscosity of the recovered fibers, a fibrous cellulose-NMMO mixture was formed, which was not suitable as a spinning solution. The fibrous cellulose NMMO mixture was subjected to the Sikarex test. This mixture did not pass the Sikarex test.
    Example 3:
    Sample 3 recovered cotton fibers from dyed consumer cotton waste material, which was in the form of cotton hemp pulp, was subjected to an acidic wash treatment according to the present invention. Acid washing was carried out at a pH of 3 at a temperature of 60 ° C for 15 minutes. The sample was dehydrated and washed with deionized water. Thereafter, Sample 3 was subjected to oxidative bleaching by means of hydrogen peroxide according to the present invention. Hydrogen peroxide bleaching was carried out at a pH of 10.6 for 60 minutes at 80 ° C. The dose of H2O2 was 10 kg / odtp. 1 kg of Mg 2+ / odtp was added in the form of Mg (SO 4) as a bleaching assistant. Finally, the sample was dewatered, washed with deionized water and air dried.
    After sample 3 has been subjected to these treatments, the sample is designated Sample 3 A-P. The metal content was effectively lowered such that the spinning solutions made from Sample 3 A-P successfully passed the Sikarex test. The intrinsic viscosity of Sample 3 A-P was adjusted to 390 ml / g and the brightness was increased to 85.7% ISO. (1) A lyocell spinning solution was prepared from a mixture of 10% sample 3 A-P and 90% conventional chemical pulp. This spinning solution was used to make Lyocell-type regenerated cellulose fibers by treating them according to the Lyocell method, as well known to those skilled in the art, for example from EP 0356419 B1 and EP 0671492 B1.
    The corresponding fiber data is shown in Table 1.
    Example 4:
    Sample 3 was subjected to an acidic washing treatment according to the present invention as described in Example 3. Then sample 3 became oxidative
    Subjected to bleaching by ozone according to the present invention. Ozone bleaching was carried out at a pH of 2.5 for a reaction time of 10 seconds at 50 ° C. The dose O3 was 2.9 kg / odtp. Finally, the sample was dewatered, washed with deionized water and air dried.
    After sample 3 has undergone these treatments, the sample is designated Sample 3 A-Z. The metal content was effectively lowered such that the spinning solutions made from Sample 3A-Z successfully passed the Sikarex test. The intrinsic viscosity of Sample 3 A-Z was adjusted to 371 ml / g and the brightness was increased to 82.4% ISO.
    Example 5:
    Sample 4, recovered cotton fibers from dyed cotton waste material prior to use by consumers, which is in the form of
    Cotton hemp pulp was subjected to oxidative bleaching by means of hydrogen peroxide according to the present invention. Thereafter, the sample 4 was subjected to an acidic washing treatment according to the present invention. Finally, the sample was dewatered, washed with deionized water and air dried.
    After sample 4 has undergone these treatments, the sample is designated as sample 4 P-A. The metal content was effectively lowered such that the spinning solutions made from Sample 4 P-A successfully passed the Sikarex test. The intrinsic viscosity of Sample 4 P-A was adjusted to 372 ml / g and the brightness was increased to 82.1% ISO. (1) A lyocell spinning solution was prepared from 100% sample 4P-A. The spinning solution was used to produce lyocell-type cellulose regenerated fibers by treating them according to the lyocell method. Corresponding fiber data are shown in Table 1. (2) A viscose spinning solution was prepared from 100% Sample 4 P-A. The spinning solution was used to make viscose-type regenerated cellulose fibers by treating according to the viscose process, as known to those skilled in the art, for example, from Gotze, "Man-made Fibers", 1967.
    Corresponding fiber data are shown in Table 1. (3) A viscose spinning solution was prepared from a mixture of 20% Sample 4 P-A and 80% conventional chemical pulp. The spinning solution was used to make viscose-type regenerated cellulose fibers by treating according to the viscose process. Corresponding fiber data are shown in Table 1.
    Example 6:
    Sample 4, after being bleached with hydrogen peroxide, was subjected to an acidic washing treatment with simultaneous addition of a complexing agent in low concentration according to the present invention. The treatment was carried out at a pH of 3 at a temperature of 60 ° C for 30 minutes. As a complexing agent, EDTA was added, the concentration being 2 kg / odtp. Finally, the sample was dewatered, washed with deionized water and air dried.
    After Sample 4 has been subjected to these treatments, the sample is called sample 4P-AQ. The metal content was effectively lowered such that the spinning solutions made from Sample 4 P-AQ successfully passed the Sikarex test. The intrinsic viscosity of Sample 4 P-AQ was adjusted to 366 ml / g and the brightness was increased to 84.5% ISO.
    Example 7:
    Sample 5 recovered cotton fibers from dyed consumer-use cotton waste material, which was in the form of cotton hemp pulp, was subjected to oxidative bleaching by hydrogen peroxide according to the present invention. Thereafter, the sample 5 was subjected to an acidic washing treatment according to the present invention. Finally, the sample was dewatered, washed with deionized water and air dried.
    After sample 5 has undergone these treatments, the sample is designated as sample 5P-A. The metal content was effectively lowered such that the spinning solutions made from Sample 5 P-A successfully passed the Sikarex test. The intrinsic viscosity of Sample 5 P-A was adjusted to 612 ml / g and the brightness was increased to 80.9% ISO. (1) A viscose spinning solution was prepared from 100% Sample 5 P-A. The spinning solution was used to make Modal type regenerated cellulose fibers by treating them according to the Modal method, as is well known to those skilled in the art, for example, from AT 287905. Corresponding fiber data is shown in Table 1.
    Example 8:
    Sample 6, untreated recovered cotton fibers from indigo denim waste material prior to consumer use, was subjected to alkaline cooking similar to the preparation of CRP. Thereafter, the sample 6 was subjected to an acidic washing treatment according to the present invention. Then, the sample 6 was subjected to an oxidative bleaching sequence according to the present invention. The bleaching sequence consisted of a Z-stage followed by a P-stage. The Z-stage was carried out at a pH of 2.5 for a reaction time of 10 seconds at 50 ° C. The dose of 03 was 5.2 kg / odtp. The bleaching of the P-stage was carried out at a pH of 10.5 for 30 minutes at 80 ° C. The dose of H2O2 was 10 kg / odtp. 1 kg of Mg 2+ / odtp was added in the form of Mg (SO 4) as a bleaching assistant. Finally, the sample was dewatered, washed with deionized water and air dried.
    After sample 6 has undergone these treatments, the sample is designated sample 6 A-Z-P. The metal content was effectively lowered such that the spinning solutions made from Sample 6 A-Z-P successfully passed the Sikarex test. The intrinsic viscosity of Sample 6 A-Z-P was adjusted to 498 ml / g and the brightness was increased to 90.3% ISO.
    Table 1: Fiber data
    Translation of the texts from FIG. 1:
    权利要求:
    Claims (21)
    [1]
    Claims 1. A process for pretreating reclaimed cotton fibers to be used in the manufacture of regenerated cellulose moldings, wherein the pretreatment of the reclaimed cotton fibers comprises a metal removal step and an oxidative bleaching step.
    [2]
    2. A method according to claim 1, wherein the cotton fibers are recovered from cotton waste accumulating prior to use by consumers.
    [3]
    3. A method according to claim 1, wherein the cotton fibers are recovered from cotton waste resulting from use by consumers.
    [4]
    The method of claim 1, wherein the recovered cotton fibers comprise cotton pulp made from cotton fibers.
    [5]
    5. The method of claim 1 wherein the recovered cotton fibers are mechanically comminuted, ground or opened prior to use.
    [6]
    6. The method of claim 1, wherein the metal removal step is an acidic wash treatment and / or a complexing agent treatment.
    [7]
    A method according to claim 6, wherein the recovered cotton fibers are treated by means of an aqueous solution of a complexing agent.
    [8]
    8. The method of claim 6, wherein by adding a complexing agent to the acidic wash treatment, both treatments are combined in one step.
    [9]
    The method of claim 1, wherein the oxidative bleaching step comprises an oxygen bleaching treatment.
    [10]
    10. The method of claim 1, wherein the oxidative bleaching step comprises a peroxide bleaching treatment.
    [11]
    11. The method of claim 1, wherein the oxidative bleaching step comprises an ozone bleaching treatment.
    [12]
    12. The method of claim 1, wherein the oxidative bleaching step comprises a sequence of oxidative bleaching treatments according to claims 9 to 11.
    [13]
    13. The use of the recovered cotton fibers obtained from the process according to claim 1 in the production of a shaped body of regenerated cellulose according to the viscose process.
    [14]
    14. A process according to claim 1, wherein the process conditions are such that the intrinsic viscosity of the recovered cotton fibers after being subjected to the process is in the range of 850 to 300 ml / g, preferably 650 to 350 ml / g, in particular of 550 to 400 ml / g, when the recovered cotton fibers according to claim 13 are to be used.
    [15]
    15. Use according to claim 13, wherein the shaped body is a staple fiber, a filament fiber, a sponge or a film of the viscose or modal type.
    [16]
    16. Use of the recovered cotton fibers obtained from the process according to claim 1 in the production of a shaped body of regenerated cellulose according to the Lyocell method.
    [17]
    17. A process according to claim 1, wherein the process conditions are such that the intrinsic viscosity of the recovered cotton fibers, after being subjected to the process, is in the range of 650 to 300 ml / g, preferably 500 to 350 ml / g, in particular of 440 to 360 ml / g, when the recovered cotton fibers according to claim 16 are to be used.
    [18]
    18. Use according to claim 16, wherein the shaped body is a staple fiber, a filament fiber, a sponge or a sheet of lyocell type.
    [19]
    19. Use according to claim 13 to 18, wherein the recovered cellulosic fibers are used in the production of a shaped body of regenerated cellulose either in pure form or in mixtures with commercially available chemical pulp.
    [20]
    20. Use according to claim 13 to 19, wherein the resulting moldings are used for further processing into textile or nonwoven products.
    [21]
    21. Products comprising regenerated cellulose articles made up to 100% of recovered cotton fibers treated according to claim 1.
    类似技术:
    公开号 | 公开日 | 专利标题
    AT515152B1|2015-12-15|A process for pretreating recovered cotton fibers for use in the manufacture of regenerated cellulose moldings
    CN100558952C|2009-11-11|Bamboo-carbon viscose fibre and manufacture method thereof
    AT517020B1|2020-02-15|Recycling of cellulosic synthetic fibers
    DE3906735C2|1999-04-15|Bleaching process
    US20200063293A1|2020-02-27|Cellulose fibers
    EP3511448A1|2019-07-17|Method for the recycling of textile material containing cellulose
    US20200165747A1|2020-05-28|Recycling of cellulosic textiles
    DE4128256C1|1993-04-15|
    AT513426A1|2014-04-15|Spun-dyed modal fiber, its use and process for its preparation
    DE546350C|1932-03-11|Process for the treatment of textile materials
    TWI715915B|2021-01-11|Functionalization of foreign substances in lyocell process
    AT505476A1|2009-01-15|Production of cellulose products e.g. artificial fiber from cellulosic raw materials containing bamboo cellulose comprises performing amine oxide method, where the bamboo cellulose contains specified concentration range of iron
    DE102005002539A1|2006-05-11|Process for bleaching, dyeing, finishing and washing silver-loaded pulps
    EP3748071A1|2020-12-09|Joint processing of lignocellulose raw material and cellulose-containing lignine-free product
    EP3747614A1|2020-12-09|Method for providing a prepared cellulose-comprising material with predetermined fibre length distribution
    EP3511371A1|2019-07-17|Reuse of insoluble particles from a cellulose precursor
    Nguyen2020|Recycling cellulosic fibres from waste textile by cellulose carbamate technology |
    JP2022514252A|2022-02-10|How to Recycle Cellulose Raw Materials from Cellulose Raw Materials and Mixed Fiber Waste
    WO2021001780A1|2021-01-07|Process for upcycling textile waste
    Haslinger2020|Towards a Closed Loop Economy in Textile Industry: Separation, Dyeing and Re-Spinning of Cellulose Rich Textile Waste
    DE879147C|1953-06-11|Process for opening up raw green bast fibers
    同族专利:
    公开号 | 公开日
    JP6488484B2|2019-03-27|
    KR102154244B1|2020-09-10|
    AT515152B1|2015-12-15|
    ES2733342T3|2019-11-28|
    TR201909108T4|2019-07-22|
    EP3074555B1|2019-03-27|
    HUE043860T2|2019-09-30|
    KR20160090874A|2016-08-01|
    US20160237619A1|2016-08-18|
    US10316467B2|2019-06-11|
    JP2016537521A|2016-12-01|
    CN105765116B|2019-02-12|
    CN105765116A|2016-07-13|
    EP3074555B9|2019-09-11|
    US20170284023A9|2017-10-05|
    EP3074555A1|2016-10-05|
    WO2015077807A1|2015-06-04|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US2211138A|1935-12-04|1940-08-13|Paper Chemistry Inst|Preparation of rags for paper making|
    CN1038471A|1988-06-10|1990-01-03|张家芳|With old cotton production new cotton technology|
    CN102677230A|2011-03-12|2012-09-19|咸立强|Environment-friendly method for producing renewable cotton|
    US20130078373A1|2011-09-26|2013-03-28|Tintoria Piana Us, Inc.|Recycling Cotton Fiber From Old Mattresses|US10093790B2|2013-10-15|2018-10-09|Lenzing Aktiengesellschaft|Three-dimensional cellulose molded body, method for the production thereof and use of the same|
    US10316467B2|2013-11-26|2019-06-11|Lenzing Aktiengesellschaft|Process for pretreating reclaimed cotton fibers to be used in the production of molded bodies from regenerated cellulose|
    US10370778B2|2015-02-06|2019-08-06|Lenzing Aktiengesellschaft|Recycling of man-made cellulosic fibers|
    US10513564B2|2013-10-15|2019-12-24|Lenzing Aktiengesellschaft|Cellulose suspension, method for the production and use thereof|FR837886A|1937-07-23|1939-02-22|Snia Viscosa|Process for the manufacture of artificial textile fibers having characteristics similar to those of rayon|
    US2647891A|1949-09-26|1953-08-04|Du Pont|Viscose recovery|
    DE907051C|1949-11-01|1954-02-11|Rayonier Inc|Process for the production of viscose from cotton, in particular linters|
    AT287905B|1968-09-20|1971-02-10|Chemiefaser Lenzing Ag|Process for the production of thread from regenerated cellulose|
    US3758457A|1972-01-25|1973-09-11|Du Pont|Process for recovering regenerated cellulose|
    US3817983A|1972-05-01|1974-06-18|Du Pont|Process using diverse types of cellulose for preparing viscose|
    US3914130A|1974-05-08|1975-10-21|Du Pont|Process for adding particulate cellulose to alkali cellulose|
    DE2735816C3|1977-08-09|1981-08-13|Basf Ag, 6700 Ludwigshafen|Process for desizing and bleaching textile goods|
    US4145533A|1978-07-26|1979-03-20|Olin Corporation|Method for recycling regenerated cellulose scrap|
    US4946953A|1986-10-16|1990-08-07|Kanebo, Ltd.|Fine cellulose particles and process for production thereof employing coagulated viscose|
    JP2627642B2|1988-06-11|1997-07-09|チッソ株式会社|Powder cosmetics|
    AT392972B|1988-08-16|1991-07-25|Chemiefaser Lenzing Ag|METHOD FOR PRODUCING SOLUTIONS OF CELLULOSE AND DEVICE FOR IMPLEMENTING THE METHOD|
    JPH02169707A|1988-12-14|1990-06-29|Kanebo Ltd|Regenerated cellulosic fiber and woven or knitted fabric thereof|
    CA2053035C|1990-10-12|1997-09-30|Repap Enterprises Inc.|Chlorine-free wood pulps and process of making|
    DE4118899C1|1991-06-08|1992-10-22|Degussa Ag, 6000 Frankfurt, De|
    US5331801A|1992-01-24|1994-07-26|Eco Fibre Canada Inc.|Recycled yarns from textile waste and the manufacturing process therefor|
    ATA53792A|1992-03-17|1995-02-15|Chemiefaser Lenzing Ag|METHOD FOR PRODUCING CELLULOSIC MOLDED BODIES, DEVICE FOR IMPLEMENTING THE METHOD AND USE OF A SPINNING DEVICE|
    FI93232C|1993-03-03|1995-03-10|Ahlstroem Oy|Method for bleaching pulp with chlorine-free chemicals|
    US6010594A|1993-03-03|2000-01-04|Ahlstrom Machinery Corporation|Method of bleaching pulp with chlorine-free chemicals wherein a complexing agent is added immediately after an ozone bleach stage|
    US5464501A|1993-04-06|1995-11-07|Societe Anonyme Pour L'etude Et L'exploitation L'air Liquide, Des Procedes Georges Claude|Bleaching recycled pulp with a reductive-oxidative sequence|
    DE4317060A1|1993-05-21|1994-11-24|Basf Ag|Process for the continuous pretreatment of cellulose-containing textile goods|
    US5447603A|1993-07-09|1995-09-05|The Dow Chemical Company|Process for removing metal ions from liquids|
    US5369861A|1994-01-21|1994-12-06|Burlington Industries, Inc.|Process for recycling denim waste|
    US5481864A|1994-07-11|1996-01-09|Wright; Herbert J.|Cloth scrap recycling method|
    AT401392B|1994-09-05|1996-08-26|Chemiefaser Lenzing Ag|METHOD FOR PRODUCING A CELLULOSIC MOLDED BODY|
    DE4444245C1|1994-12-13|1996-07-04|Hoechst Ag|Process for recycling colored, cellulosic waste products into fibers|
    AT401779B|1995-02-02|1996-11-25|Chemiefaser Lenzing Ag|Production of formed cellulose products - comprises spinning a solution of cellulose in aqueous tert.amine oxide and recycling the precipitation bath after regeneration to a specified range of pH|
    JPH08260369A|1995-03-22|1996-10-08|Mitsubishi Paper Mills Ltd|Method of highly whitening waste paper pulp|
    AT408547B|1995-09-26|2001-12-27|Chemiefaser Lenzing Ag|METHOD FOR TRANSPORTING A SOLUTION OF CELLULOSE IN AN AQUEOUS TERTIARY AMINOXIDE|
    GB9617043D0|1996-08-14|1996-09-25|Courtaulds Plc|Manufacture ofd extruded articles|
    US6471727B2|1996-08-23|2002-10-29|Weyerhaeuser Company|Lyocell fibers, and compositions for making the same|
    CA2264180C|1996-08-23|2009-09-01|Mengkui Luo|Lyocell fibers and process for their preparation|
    US6306334B1|1996-08-23|2001-10-23|The Weyerhaeuser Company|Process for melt blowing continuous lyocell fibers|
    WO1998022642A1|1996-11-21|1998-05-28|Toyo Boseki Kabushiki Kaisha|Regenerated cellulosic fibers and process for producing the same|
    JP3852631B2|1997-05-29|2006-12-06|東洋紡績株式会社|Regenerated cellulose fiber and method for producing the same|
    AT405949B|1997-06-05|1999-12-27|Chemiefaser Lenzing Ag|REGENERATED CELLULOSIC SHAPED BODY|
    AU7042200A|1999-07-14|2001-01-30|Grupo Cydsa, S.A. De C.V.|Process for the fabrication of activated cellulose and derivatives thereof|
    US7052578B2|2000-01-28|2006-05-30|Martin Marietta Magnesia Specialties, Inc.|Process employing magnesium hydroxide in peroxide bleaching of mechanical pulp|
    JP2001316937A|2000-05-10|2001-11-16|Toyobo Co Ltd|Method for producing cellulose formed article|
    US6378179B1|2001-01-05|2002-04-30|Gary F. Hirsch|System and method for reconstituting fibers from recyclable waste material|
    DE10102334C2|2001-01-19|2003-12-04|Thueringisches Inst Textil|Process for the production of regular, monodisperse cellulose beads and their use|
    JP3937216B2|2002-03-18|2007-06-27|東洋紡績株式会社|Method for producing cellulose molded body|
    US7132469B2|2002-06-28|2006-11-07|Reinforced Polymers, Inc.|Molding compositions with solid thermoplastic elastomer thickeners and products obtained therefrom|
    US20040131690A1|2002-09-20|2004-07-08|Lynch Maurice Gerard|Beads and methods of preparation|
    WO2004043329A2|2002-11-12|2004-05-27|L'oreal|Use of cellulose microbeads to make the skin matt|
    FI117393B|2003-01-10|2006-09-29|Kemira Oyj|Process for bleaching cellulose fiber material|
    AU2003901396A0|2003-03-25|2003-04-10|Commonwealth Scientific And Industrial Research Organisation|Methods for bleaching of cellulosic materials|
    US6833187B2|2003-04-16|2004-12-21|Weyerhaeuser Company|Unbleached pulp for lyocell products|
    JP4195689B2|2004-09-09|2008-12-10|セーレン株式会社|Method for producing composite fiber product comprising cotton and regenerated cellulose fiber|
    AT502993B1|2005-12-19|2008-07-15|Chemiefaser Lenzing Ag|METHOD FOR PRODUCING A DYED CELLULOSIC FORM BODY|
    US7390566B2|2006-06-30|2008-06-24|Weyerhaeuser Company|Viscose product|
    FI119375B|2007-02-02|2008-10-31|Kemira Oyj|A novel composition and method for treating fibrous material|
    WO2009037146A1|2007-09-17|2009-03-26|Basf Se|Crosslinked cellulose beads|
    AT505905B1|2007-09-21|2009-05-15|Chemiefaser Lenzing Ag|CELLULOSE POWDER AND METHOD FOR THE PRODUCTION THEREOF|
    GB0721587D0|2007-11-02|2007-12-12|Innospec Ltd|Process for bleaching pulp|
    US20100297445A1|2007-11-22|2010-11-25|Basf Se|Production of spherical particles from solutions comprising a water-miscible solvent by the method of underwater pelletization|
    AT507758A1|2008-12-23|2010-07-15|Chemiefaser Lenzing Ag|YARN AND THREADS FROM BLENDS OF FIBERS AND ARTICLES THEREFROM|
    WO2011077446A1|2009-12-23|2011-06-30|Varun Gambhir|Process for recycling cotton fabrics|
    WO2011130276A2|2010-04-12|2011-10-20|Enova Textile And Apparel, Llc|Processes for using recycled waste cotton material in producing a textile product and textile products produced form waste cotton material|
    WO2012002729A2|2010-06-30|2012-01-05|코오롱인더스트리 주식회사|Dope for spinning lyocell, method for preparing a lyocell filament fiber using same, and method for preparing a lyocell staple fiber using same|
    JP6003080B2|2011-02-21|2016-10-05|三菱化学株式会社|Cellulose fiber and method for producing cellulose fiber|
    CA2828980C|2011-03-08|2019-02-26|Sappi Netherlands Services B.V.|Method for dry spinning neutral and anionically modified cellulose and fibres made using the method|
    DE102011101321A1|2011-05-12|2012-11-15|Glanzstoff Bohemia S.R.O.|Flame-retardant cellulose regenerated filament fibers and process for its preparation|
    CN102199310B|2011-05-17|2013-01-02|东华大学|Method for recycling cotton-containing components in waste cotton-polyester blended fabrics|
    AT511624B1|2011-07-13|2014-02-15|Chemiefaser Lenzing Ag|CELLULOSE II SUSPENSION, THEIR PREPARATION AND STRUCTURES MADE THEREFROM|
    AR088787A1|2011-08-30|2014-07-10|Cargill Inc|PULP COMPOSITION|
    CN104169491B|2012-02-20|2015-11-25|勒纽赛尔卢克斯责任有限公司|Regenerated cellulose|
    CN102660791A|2012-04-15|2012-09-12|广东巨洋环保科技有限公司|Old clothes recovery method|
    CN104379833B|2012-05-28|2016-05-11|索德拉细胞公司|New technology and the dissolving pulp of manufacturing by this technique|
    CN104411881B|2012-07-06|2015-11-25|日本制纸株式会社|Regenerated fiber and regenerated fiber products formed|
    AT515152B1|2013-11-26|2015-12-15|Chemiefaser Lenzing Ag|A process for pretreating recovered cotton fibers for use in the manufacture of regenerated cellulose moldings|
    TWI667378B|2014-01-03|2019-08-01|奧地利商蘭精股份有限公司|Cellulosic fibre|
    US20160369456A1|2014-04-17|2016-12-22|Evrnu, Spc|Methods and systems for processing cellulose-containing materials and isolating cellulose molecules; methods for regenerating cellulosic fibers|
    AT517020B1|2015-02-06|2020-02-15|Chemiefaser Lenzing Ag|Recycling of cellulosic synthetic fibers|WO2017214477A1|2016-06-09|2017-12-14|Board Of Regents, The University Of Texas System|Cotton recycling|
    SE541675C2|2016-10-19|2019-11-26|Re Newcell Ab|Recycling of cellulosic textiles|
    US10588369B2|2016-10-21|2020-03-17|The Board Of Regents For Oklahoma State University|Textile repurposing and sustainable garment design|
    CN110546317A|2016-12-06|2019-12-06|雷纽赛尔公司|Cellulose fiber|
    EP3339504A1|2016-12-22|2018-06-27|Lenzing Aktiengesellschaft|Method of pulping cotton-based raw material|
    EP3538691A1|2016-12-23|2019-09-18|Spinnova Oy|A fibrous monofilament|
    FR3075227B1|2017-12-18|2020-11-13|Association Pour Le Developpement De Lenseignement Et Des Recherches Aupres Des Univ Des Centres De|PROCESS FOR MANUFACTURING A CARBON FIBER FROM RECYCLED COTTON AND USE OF THE FIBER SO OBTAINED FOR THE FORMATION OF AN ARTICLE IN COMPOSITE MATERIAL|
    EP3511447A1|2018-01-15|2019-07-17|Lenzing Aktiengesellschaft|Functionalization of foreign substances in lyocell method|
    EP3511448A1|2018-01-15|2019-07-17|Lenzing Aktiengesellschaft|Method for the recycling of textile material containing cellulose|
    SE543048C2|2018-12-19|2020-09-29|Re Newcell Ab|A method for separating cellulosic fibers from non-cellulosic fibers|
    EP3670010A1|2018-12-21|2020-06-24|Lenzing Aktiengesellschaft|Method for recycling a cellulose raw material from blended textile waste and cellulose raw material produced thereby|
    WO2021001780A1|2019-07-03|2021-01-07|Grasim Industries Limited|Process for upcycling textile waste|
    WO2021006798A1|2019-07-05|2021-01-14|Kiram Ab|Method for dissolving pulp from recycled textile material|
    CN110359143B|2019-07-26|2020-11-17|际华三五四二纺织有限公司|Pure bamboo Daer high count yarn|
    WO2021094993A1|2019-11-14|2021-05-20|Glycom A/S|Synthetic composition for balancing the bile acid profile in the intestine|
    WO2021115931A1|2019-12-13|2021-06-17|Lenzing Aktiengesellschaft|Process for recovering starting materials from mixed textile wastes|
    EP3835023A1|2019-12-13|2021-06-16|Lenzing Aktiengesellschaft|Method for recycling components comprised of mixed textile waste|
    CN111304767A|2020-02-17|2020-06-19|河北吉藁化纤有限责任公司|Preparation method for producing regenerated cellulose fiber by using waste textile regenerated pulp and regenerated cellulose fiber|
    EP3882380A1|2020-03-16|2021-09-22|Re:NewCell AB|One stage method for acid metal removal and bleach|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA905/2013A|AT515152B1|2013-11-26|2013-11-26|A process for pretreating recovered cotton fibers for use in the manufacture of regenerated cellulose moldings|ATA905/2013A| AT515152B1|2013-11-26|2013-11-26|A process for pretreating recovered cotton fibers for use in the manufacture of regenerated cellulose moldings|
    ES14828434T| ES2733342T3|2013-11-26|2014-11-18|Process for pretreating recovered cotton fibers to be used in the production of molded bodies from regenerated cellulose|
    PCT/AT2014/000205| WO2015077807A1|2013-11-26|2014-11-18|Process for pretreating reclaimed cotton fibres to be used in the production of moulded bodies from regenerated cellulose|
    KR1020167017024A| KR102154244B1|2013-11-26|2014-11-18|Process for pretreating reclaimed cotton fibres to be used in the production of moulded bodies from regenerated cellulose|
    JP2016532639A| JP6488484B2|2013-11-26|2014-11-18|Method for pretreating recovered cotton fibers used in the production of shaped bodies from regenerated cellulose|
    EP14828434.2A| EP3074555B9|2013-11-26|2014-11-18|Process for pretreating reclaimed cotton fibres to be used in the production of moulded bodies from regenerated cellulose|
    CN201480064674.6A| CN105765116B|2013-11-26|2014-11-18|For pre-processing the method for the recycling cotton fiber by regenerated cellulose production formed body|
    TR2019/09108T| TR201909108T4|2013-11-26|2014-11-18|Process for pretreatment of recycled cotton fibers to be used in the production of molded bodies from regenerated cellulose.|
    HUE14828434A| HUE043860T2|2013-11-26|2014-11-18|Process for pretreating reclaimed cotton fibres to be used in the production of moulded bodies from regenerated cellulose|
    US15/027,945| US10316467B2|2013-11-26|2014-11-18|Process for pretreating reclaimed cotton fibers to be used in the production of molded bodies from regenerated cellulose|
    [返回顶部]